icon caches (created by gtk-update-icon-cache) are currently detected as application/x-font-ttf by the pattern freedesktop.org.xml:5706 <match value="\000\001\000\000\000" type="string" offset="0"/> imho this pattern is much to simple and should be removed/expanded (icon cashes happen to match this pattern because their header contains the version number 1.0.12 with 16bit-ints for each part). icon cache files could be detected by <glob pattern="*.cache"/> or even <treematch type="file" path="icon-theme.cache" match-case="true"/> as this name seems to be canonical.
No real way to work around this problem, except GTK+ adding a proper magic header to its caches. Filed as https://bugzilla.gnome.org/show_bug.cgi?id=651067
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